Activation of H2 by a highly distorted Rh(II) complex with a new C3-symmetric tripodal tetraphosphine ligand.

نویسندگان

  • Jeroen Wassenaar
  • Bas de Bruin
  • Maxime A Siegler
  • Anthony L Spek
  • Joost N H Reek
  • Jarl Ivar van der Vlugt
چکیده

Facile oxidation of a sterically encumbered Rh(I) complex generates a stable Rh(II) metalloradical species; the latter is able to activate H(2) under formation of the corresponding Rh(III) complex.

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عنوان ژورنال:
  • Chemical communications

دوره 46 8  شماره 

صفحات  -

تاریخ انتشار 2010